Yesterday I took my 37.5 mg at about 8:30 and it lasted pretty much all day. I didn't eat breakfast until about 10 and I ate dinner at 5:30. I wasn't hungry for the rest of the day.
I think that the pill works differently for everyone though. The best way to tell what time you should be taking your pill would probably be by trial and error.
Good luck with your weight loss goals! 
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